Identifying Eigen-like hydrated protons at negatively charged interfaces

Eric Tyrode, Sanghamitra Sengupta and Adrien Sthoer

Aug 30, 2019

Received Date: 23rd August 19

Despite the importance of the hydrogen ion in a wide range of biological, chemical, and physical processes, its molecular structure in solution remains lively debated. Progress has been primarily hampered by the extreme diffuse nature of the vibrational signatures of hydrated protons in bulk solution. Using the inherently surface-specific vibrational sum frequency spectroscopy, we show that at selected negatively charged interfaces, a resolved spectral feature directly linked to the H3O+ core in an Eigen-like species can be readily identified in a biologically compatible pH range. The results offer a new molecular perspective for tracking and understanding the behaviour of hydrated protons at interfaces.

Read in full at ChemRxiv.

This is an abstract of a preprint hosted on an independent third party site. It has not been peer reviewed but is currently under consideration at Nature Communications.

Nature Communications

Nature Research, Springer Nature