Probing multiphoton light-induced molecular potentials

M. Kübel, M. Spanner, Z. Dube, A.Yu. Naumov, S. Chelkowski, A.D. Bandrauk, M.J.J. Vrakking, P.B. Corkum, D.M. Villeneuve, and A. Staudte

Jul 16, 2019

Received Date: 28th June 19

The strong coupling between intense laser fields and valence electrons in molecules causes a distortion of the potential energy hypersurfaces which determine the motion of nuclei in a molecule and influences possible reaction pathways. The coupling strength varies with the angle between light electric field and valence orbital, and thereby adds another dimension to the effective molecular potential energy surface, allowing for the emergence of light-induced conical intersections. Here, we demonstrate in theory and experiment that the full complexity of such light induced potential energy surfaces can be uncovered. In H2+, the simplest of molecules, we observe a strongly modulated angular distribution of protons which has escaped prior observation. These modulations directly result from ultrafast dynamics on the light-induced molecular potentials and can be modified by varying the amplitude, duration and phase of a mid-infrared dressing field. This opens an interesting route for manipulating the dissociation of small molecules using strong laser fields.

Read in full at arXiv.

This is an abstract of a preprint hosted on an independent third party site. It has not been peer reviewed but is currently under consideration at Nature Communications.


Nature Communications

Nature Research, Springer Nature